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Self-Assembled “the intramolecular enolate oxidative couplingreaction

J. AM. CHEM. SOC. 2010, DOI: 10.1021/ja106739g
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文献汇报人:张振

汇报日期: 2018930

图文摘要:


  • 推荐原因:

烯醇负离子氧化偶联反应早在1935 年就已经有报道,各种含羰基的官能团如酸、酯、酮、酰胺甚至吲哚等都能参与该反应。由于分子间反应趋于发生自身二聚及多聚反应,但分子内反应可以很好地控制化学选择性,获得较好的收率。该类方法能够高效地构建1,4-二羰基官能团,在合成上有着较广的应用。


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