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A brief introduction to Ph.D Sergey V Pronin’s Recent works

J.Am.Chem.Soc.2015,137,15410 full text link

J. Am. Chem. Soc. 2016, 138, 12316−12319 full text link

J. Am. Chem. Soc. 2018, 140, 12770-12774
full text link

文献汇报人:谌雪鸣

汇报日期: 201976

图文摘要:

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  • 推荐原因:

    Sergey V. Pronin 小组近三年的工作对蕈青霉素类二萜化合物进行了系统地探究,成功使用HAT反应构筑了二萜核心骨架。并通过添加邻近基团地参与,调控了分子内的 aldol缩合反应,实现了立体选择性地改良,在2015年发表在JACS上。该组从反应前体合成中汲取经验,系统探究了烯醇硅醚与末端炔在InBr3催化下的偶联反应,在次年的JACS上发表。基于2015年的工作,其课题组对蕈青霉素衍生物Nodulisporic acids类化合物进行了合成研究。主要探索了π酸催化的炔烃与烯烃的合环,该反应一步构筑了两个环且收率高。这些工作关联性强且想法十分新颖。


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