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Self-Assembled “Artificial Diels–Alderase

JACS 2018, DOI: 10.1021/jacs.8b09685
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文献汇报人:刘昭

汇报日期: 2018128

图文摘要:

 


  • 推荐原因:

本文是首次对映选择性合成 mitrephorone A。文章中用到很多经典反应,比如光催化[2 + 2]环加成,D-A反应,Prins环化等。其中,D-A反应快速构建关键碳环,高价碘氧化构建带三个季碳的高张力四环醚都给人耳目一新的感觉。


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