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Total Syntheses of Bisdehydroneostemoninine and Bisdehydrostemoninine by Catalytic Carbonylative Spirolactonization

Angew. Chem. Int. Ed. 2018, 57, 15209-15212, DOI:10.1002/anie.201809114 full text link

文献汇报人:郑少龙

汇报日期: 20181230

图文摘要:


  • 推荐原因:
    文章通过羟基环丙烷的钯催化的羰基化螺环内酯化一步来构建天然产物分子的关键骨架,从而又快又好地实现天然产物Bisdehydroneostemoninine (1a)和Bisdehydrostemoninine (1b)的合成,此插羰反应适用于多种天然产物分子骨架的构建,值得学习研究。

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