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Asymmetric Total Synthesis of Cyclocitrinol

J. Am. Chem. Soc. 2018, 140, 5365−5369 DOI: 10.1021/jacs.8b02629 full text link


汇报日期: 2019622



  • 推荐原因:李闯创教授通过自己课题组发展的type II型分子内环加成反应构建了双环[4.4.1]桥环骨架,并基于此完成了天然产物Cyclocitrinol 的首次不对称全合成。整个合成过程简洁高效。

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